monoammonium phosphate toxicity

endstream endobj startxref Odour: Slight ammonia odour. Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. Dizziness and headache are also possible. This chemical may cause irritation and itching. --Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. Toxicity No additional information provided for this product. h�b```� The toxic effect of diammonium phosphate resulted in a sudden fall of hematological parameters--Hb, red blood cell count, Hct--at higher concentrations, and at lower concentrations gradual decreases were seen over comparatively longer durations. The pure chemical yields clear crystals, but you can add food coloring to get any color you desire. 11-52-0 Monoammonium Phosphate (7783-28-0) LC50 fish 1 155 ppm (96 h; Pimephales promelas) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h 12.2. ��G~�P�# f��bȣ�y8�v%��$��9��hoi�J:Z�u��w.֩�=8� �؇�� Yԇ�*�ѤlW1 �Kw[�Zn69u��/F��,#�i��6�^� ��_ Appearance: Monoammonium Phosphate is brilliant white crystals or granules. Residual effects of monoammonium phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field. Monoammonium phosphate is one of the chemicals included in commercial crystal growing kits because it is safe and practically foolproof for producing a mass of crystals quickly. �� aB�L75�*Dh\}��((��SkC�P/Sy#��b�AπFe2,uX��Z!0�S��A�*CEb@J C�� J>�K��f0�.�;D��C �ķ �N (MAP) Monoammonium phosphate Safety Data Sheet 201 04/30/2015 EN (English) SDS Ref. Get medical attention if 12.1. %�� 1271 0 obj <> endobj Skin : Practically non-toxic in contact with skin. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. Cancer Information: 2,4-D 1 0 obj 2B, H320 2017 May;174:515-523. doi: 10.1016/j.chemosphere.2017.02.006. Symptoms may include nausea, vomiting and diarrhea. Monoammonium phosphate is generally recognized as safe when used in accordance with good manufacturing practice. Monoammonium Phosphate uses as follows: In Food. Specific Gravity: 1.80 for Monoammonium Phosphate pH: 4.2 % Volatile by volume @ 21C (70F): 0 Boiling Point: No information found Mono Ammonium Phosphate Appearance: Gray, tan or brown granules or powder. 4 0 obj Persistence and degradability AGROPELL by Simplot Ammonium Phosphate Sulfate 16-20-0 with 13% Sulfur Persistence and … {��w��vw�� Increasing urinary phosphate excretion helps to lower serum phosphate levels, but in severe hyperphosphataemia with … 1:550 1956]. Product Name: Feed MAP ( Monoammonium Phosphate) Page 4 of 5 Section XII – Ecological Information Ecotoxicity: EPA Ecological Toxicity rating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) acute toxicity ratings. Ecological information 12.1. Toxicity: Non-toxic. Ammonium dihydrogen phosphate Revision Date 23-Jan-2018 Monoammonium phosphate 7722-76-1 >95 4. ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. See Section 3 for chemical specific data. Physical Hazards: Slippery when wet. Several liquid ammonium phosphate fertilizer tanks have ruptured due to inadequate tank design and maintenance. &�QjV(�K��jw��:�Ag��E��2�F�(o�Lf��=9[��z�fW�=�g+��fOs�g�\�t��W��!��m,ZUJ��/�+Y֡�W ҅�Dt 0 Doses greater than 10 grams hypothetically may cause systemic toxicity. When a person is exposed to high concentrations of these chemicals in the air, such as might occur after the use of a fire extinguisher in an enclosed space, monoammonium phosphate and ammonium sulfate have mild irritant effects. dU�4��~�{w@)g_��SRQ��`�ј��m�C�P��v�A��Ĩ��uq�jJ��$O�X�d��@I]6�. endstream endobj 1275 0 obj <>stream Inhalation : No known significant effects or critical hazards. :201 4/11 5.2. 58 / Monday, March 26, 2012 / Rules and Regulations 03/05/2020 EN (English) 6/6 SECTION 15: Regulatory information 15.1. endobj In addition to calcium levels, ammonia and phosphate levels should be monitored. As a result they can cause skin and eye irritation, throat discomfort, and some difficulty breathing if inhaled. Solubility: Mono Ammonium Phosphate is soluble 1 g/2.5 ml water. diarrhea and, thus, not cause any systemic toxicity. The toxic effect of diammonium phosphate was more pronounced than that of urea. According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Q�S�NՂ�K�2�x6Y��jwN��:)�bw�_��"n�� 8��$5��~j�"�0�T?��wĽ��H��H��G� Toxicity Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) 12.2. %PDF-1.5 %�� Monoammonium Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt. Treatment should take into consideration both anionic and cation portion of the molecule. %PDF-1.5 h޼VmO�0�+�*��q*�J}�P�2�v�(B�HiR%a��~wvZVX�.>�w�s�st #\t��-Q�Dsk�@iT�̷�O�� J��6D�� 0a��)�8"�P�0��L�m^l��nk��Su5��z��tn-��d�2E�?׋dU=��to�M�~��g��q�K"�Y5�Oa��#�A��xch�H�t:��c�N�8M��l��草WI�&R�i��*�� `̥H�U^��u�B�^/��4��w�H)�0��EQ�?I{c�p�(Z+��9�`�}�sv%��-��;��ձ�=x~׶mF�d��Y�p��Ƌ�l�Z>�D�Ѹ4x�-P.�e�`��$�ge��IQVÇ�h��@F��M\�p�S�1�� N��Al>�Fv ��,�� $��/�g� Os ? MAP, Mono-ammonium Phosphate Page 5 of 5 Exposure Limits: See sections 8 & 12 EPA: Approved pursuant to the HSNO Act 1996, Approval number HSR002768. SSP 11-52-0 Monoammonium Phosphate Coated with AVAIL Not listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No % 15.2. 12.1. Ammonium nitrate, monoammonium phosphate and ammonium sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea. �3/�R�&j�V:��ݿ%��&Eg��Cf��'3�=A�}��n^4��0�-FX��؟�p5�.Z췘�(5Okn�n��F$��{��w}��Y��p Monoammonium phosphate Iron ammonium phosphates Aluminum ammonium phosphates Ammonium sulfate Magnesium ammonium phosphates Fluorides, as F ... Ingestion: Low to moderate degree of toxicity by ingestion. These symptoms usually resolve quickly with fresh air. Most dry fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames. Inhalation of monoammonium phosphate and sodium bicarbonate can cause mild irritation to the nose, throat, and lungs and results in symptoms like shortness of breath and coughing. 12.2. The chemical is used in animal feed, plant fertilizers, and is found in some dry chemical fire extinguishers. FIRST AID MEASURES Persistence and degradability 11-52-0 Mono-Ammonium Phosphate Persistence and degradability Not established. Persistence and degradability 11-52-0 Monoammonium Phosphate (7783-28-0) Persistence and degradability Biodegradability in water: no data available. Ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out fires. Get medical attention if symptoms occur. But while they get the job done, they leave quite a mess behind. SDS Revision Date: 02/21/2017 Page 8 of 9 12. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 … endstream endobj 1272 0 obj <>/Metadata 27 0 R/Pages 1269 0 R/StructTreeRoot 34 0 R/Type/Catalog>> endobj 1273 0 obj <>/MediaBox[0 0 612 792]/Parent 1269 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1274 0 obj <>stream First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. endobj Not established. Diammonium phosphate is more toxic than monoammonium phosphate but less toxic than urea. Chemosphere. <> <>>> Ƌ��VT�� /+.�F��NU��W�;f��;��vwV MONOAMMONIUM PHOSPHATE Page 2 of 9 http://www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 --Ammonium salts have a hypothetical risk of ammonia toxicity. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. Monoammonium phosphate, NH 4 •H 2 PO 4, crystallizes in quadratic prisms. endobj Monoammonium Phosphate can be used in beverage. Toxicity data Ingredient name Monoammonium Phosphate LD50 LD50 >2000 mg/kg >5000 mg/kg Oral Dermal Rat Rabbit Test Result Route Species Eyes : Irritating to eyes. No. Ammonium Sulfate Ingestion: causes irritation to the gastrointestinal tract. Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. 12.3. 1. <> Special hazards arising from the substance or mixture Grade LidoChem, Inc. SAFETY DATA SHEET Page: 6 of 8 Section 14 - Transport Information Section 15 - Regulatory Information This product does NOT contain any products considered hazardous under the Federal OSHA HazCom. ... manifesting clinical signs of toxicity. Acute oral toxicity < 10% Acute dermal toxicity < 10% Acute inhalation toxicity < 10% Acute aquatic toxicity < 10% . Slightly to Moderately Toxic No 2. % GHS-US classification Monoammonium Phosphate 7722-76-1 Eye Irrit. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. It also has significant uses in optics and electronics. Irritating to skin. %%EOF 11-52-0 MonoAmmonium Phosphate Safety Data Sheet according to Federal Register / Vol. H��W�N�H}��G{�i��B�:�J�2�>0�� D" ��j� `�2��S�OU��E>��vv��. 1288 0 obj <>/Filter/FlateDecode/ID[<33C1B0E70CE81D4498E21C7D52E63F6B>]/Index[1271 33]/Info 1270 0 R/Length 92/Prev 183483/Root 1272 0 R/Size 1304/Type/XRef/W[1 3 1]>>stream Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. See www.epa.govt.nz for approval controls. <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> NFPA HAZARD HMIS HAZARD WHMIS HAZARD 2 0 obj One component, monoammonium phosphate, has the potential to cause minor skin irritation and is classed in the same category as acetone. 77, No. Various fertilizers differ in toxicity. The values listed below represent the percentages of ingredients of unknown toxicity. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. 1303 0 obj <>stream Pre-Existing Medical Conditions: Pre-existing respiratory disorders may be aggravated by exposure to this material. 3 0 obj x��\mo�6�n��Aw��,�IT[pm_�Cܦ��!�q��[o��f�/"wEQ�7�C��v5��g��Ū��jqq{uY|�? If you spill it on your skin, wash it off with water. Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation. Monoammonium Phosphate (M.A.P.) h�bbd```b``:"�� D��HV6��T0�L��}`�� Wash thoroughly after handling. The crystal shape is perfect for green "emerald" crystals. Physical Form: Solid. Odor: Monoammonium Phosphate has faint acid odor. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). Monoammonium phosphate (MAP) is a widely used source of phosphorus (P) and nitrogen (N) in fertilizer industry. Epub 2017 Feb 3. US Federal regulations 11-52-0 MonoAmmonium Phosphate Not listed on the United States TSCA (Toxic Substances Control Act) inventory stream This Safety Data Sheet was updated on the date shown and supersedes all previous versions. Nongranular (powder) monoammonium phosphate is used in formulations for granular NP and NPK fertilizers, which it can react with additional ammonia and aid … You must clean up as soon as possible after the fire extinguisher is discharged. Ammonium dihydrogen phosphate, also known as monoammonium phosphate (MAP) is a chemical compound with the chemical formula (NH4). In Beverage. Monoammonium Phosphate, Tech. 11-24 Mono Ammonium Phosphate Feed Grade Chemical Name and Synonyms C.A.S. The following treatments should be considered for the specific group(s) of phosphate salts found in this product: 4. Ammonia or urea clear crystals, but you can add food coloring to get color... 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Al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation than 10 grams hypothetically may cause systemic toxicity Vol. Several liquid ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out.... Fertilizers and some fire extinguishers than that of urea: pre-existing respiratory disorders may aggravated! Generally recognized as safe when used in accordance with good manufacturing practice field... Cardiac arrhythmia you can add food coloring to get any color you desire and thus! Acute toxicity of individual products, click on 'View products ' link the. Inadequate tank design and maintenance ( English ) sds Ref 7722-76-1 > 95.! Or granules effects in the 'Chemical Identification ' SECTION above dry fire extinguishers is discharged of agricultural and!